Leakage-Safe Machine Learning for Hydrogen Embrittlement Detection in 316L Stainless Steel: A Region-Held-Out Evaluation of Texture and Deep Features in SEM Micrographs

Muhammad Awais, Muhammad Yaseen, Abdul Shakoor, Niaz Ahmed Niaz, Huria Zia +1

Scanning electron microscopy (SEM) is routinely used to characterize the microstructural changes caused by hydrogen embrittlement (HE) in structural steels. Machine learning can automate this characterization, but models are often evaluated using image-level splits. When several images come from the same specimen region, such splits leak information between the training and test sets. Here, we propose a region-held-out protocol for classifying as-received (AR) and hydrogen-charged (H2) SEM micrographs of 316L stainless steel, based on Leave-One-Region-Out (LORO) cross-validation over 14 spatial regions (8 AR, 6 H2; 31 images). We compared six feature-classifier combinations built on local binary patterns (LBP), grey-level co-occurrence matrices (GLCM), self-supervised convolutional embeddings pretrained on 143 unlabeled SEM images, and a convolutional neural network (CNN). The simplest texture approach, LBP with a support vector machine (LBP+SVM), performed best, achieving a balanced accuracy of 0.79, H2 recall of 0.69, and H2 precision of 0.82, outperforming every deep-learning and combined-feature model. A group-level permutation test (500 permutations sampled from the 3,003…