Data-Driven Modeling of Molten Chloride Corrosion Using Static Test Data

Md Mahmudul Hasan Pathik

Molten chloride corrosion has been studied for decades, yet reliable prediction across different alloys, salts, and test conditions remains difficult. In this work, 291 static molten chloride corrosion experiments reported in the literature were compiled into a structured dataset and used to develop an interpretable machine-learning framework for corrosion-rate predictions. To better represent the differences in salt condition across studies, a Chloride Salt Preparation Index (CSPI) was introduced to bring the reported salt-treatment method, atmosphere control, and pre-exposure impurity condition on a common numerical scale. A blended tree-based ensemble provided the most consistent predictive performance, achieving a cross-validated \(R^2\) of 0.85 and an MAE of 0.41 mg cm\(^{-2}\) day\(^{-1}\). The graded CSPI retained more useful information than a simple purified/unpurified classification and emerged as the dominant model descriptor. Global sensitivity and SHAP analyses further identified exposure time, temperature, and alloy chemistry as important contributors to the model predictions, with several observed trends consistent with the established molten-chloride corrosion…